Some Observations on the Effect of the Interaction of Tantalum with Oxygen, Nitrogen, and Hydrogen

Some Observations on the Effect of the Interaction of Tantalum with Oxygen, Nitrogen, and Hydrogen
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钽与氧、氮、氢相互作用影响的一些观察

DOI:
10.1149/1.2428665
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发表时间:
1958
期刊:
影响因子:
--
通讯作者:
R. Bakish
R. Bakish
中科院分区:
--
文献类型:
--
作者:
R. Bakish

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钽与O~,N ~,和H~。{100}是反应产物的惯习面,分别为Ta~ Os、TaN和~ TaH。评价了气体-金属相互作用对单晶断裂行为的影响。讨论了观察到的{100}和{110}解理型断裂的这种相互作用引起的和一个假设来解释发生先进。描述了在解理面上观察到的痕迹。许多研究者已经详细研究了钽与氧、氮和氢的相互作用(1-4)。然而,这种互动的几个方面被完全忽视了,本次交流试图弥补其中的一些差距。本研究中使用了来自Fansteel Metallurgical Corporation的片状和线状的高纯Ta(0.03 C max,0.03 Fe max,99.9+ Ta)。对细颗粒材料和约0.01英寸的片状单晶都进行了观察。通过应变退火生长的厚度。
Experiments and results on the interaction of tantalum with O~, N.~, and H~ are presented. The {100} is shown to be the habit plane of the segregation of the reaction products which appear to be Ta~ Os, TaN, and~ TaH, respectively. The role of the gas-metal interaction on the fracture behavior of single crystals has been evaluated. The observed {100} and {110} cleavage-type fractures as induced by this interaction are discussed and a hypothesis to explain occurrence advanced. Markings observed on cleavage faces are described.The interaction of tantalum with oxygen, nitrogen, and hydrogen has been studied in some detail by a number of investigators (1-4). Several aspects of this interaction have been completely neglected, however, and an attempt to cover some of these gaps is made with this communication. High-purity Ta in sheet and wire form from Fansteel Metallurgical Corporation (0.03 C max, 0.03 Fe max, 99.9+ Ta) was used in this investigation. Observations were made both on fine grain material and on sheet single crystals of about 0.01 in. thickness grown by strain annealing.