Cellulose Solvents - Remarkable History, Bright Future
Cellulose Solvents - Remarkable History, Bright Future
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DOI：
10.1021/bk-2010-1033.ch001
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发表时间：
2010
期刊：
影响因子：
--
通讯作者：
T. Liebert
中科院分区：
文献类型：
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作者：
T. Liebert
本文总结了纤维素的溶解和使用这些纤维素解决方案的分析，再生，和聚合物的均匀改性的不同方法。水和非水溶剂，熔体，和可溶性纤维素中间体进行了讨论，重点是纤维素的成型和均匀转化的新发展。它将表明，这些媒体开辟了新的途径，纳米结构的再生纤维素和定制的纤维素衍生物无法通过非均相反应。此外，将说明通过在纤维素溶剂中转化可获得的具有新结构特征的常规纤维素产品的制备。
The paper summarizes different approaches for the dissolution of cellulose and the use of these cellulose solutions for analysis, regeneration, and homogeneous modification of the polymer. Aqueous and non-aqueous solvents, melts, and soluble cellulose intermediates are discussed with the focus on new developments for the shaping and the homogeneous conversion of cellulose. It will be shown that these media open up new paths towards nanostructured regenerated cellulose and tailored cellulose derivatives not accessible via heterogeneous reactions. Moreover, the preparation of conventional cellulose products with new structural features obtainable by conversion in cellulose solvents will be illustrated.