Nonaromatic amidine derivatives as acylation catalysts

Nonaromatic amidine derivatives as acylation catalysts
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DOI:
10.1021/ol0623419
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发表时间:
2007-01-04
期刊:
影响因子:
5.2
通讯作者:
Han, Zhenfu
Han, Zhenfu
中科院分区:
化学1区
文献类型:
--
作者:
Birman, Vladimir B.;Li, Ximin;Han, Zhenfu

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非芳香族双环脒和双环异硫脲在酰化反应中的催化活性被发现是显着依赖于两个环的大小。DBN及其硫类似物(THTP)是一类高活性的酰化催化剂。
Catalytic activity of nonaromatic bicyclic amidines and bicyclic isothioureas in acylation reactions was found to be remarkably dependent on the sizes of both rings. DBN and especially its thia-analogue (THTP) have been identified as highly active acylation catalysts.