The Structure of Monocrotaline, the Alkaloid in Crotalaria Spectabilis and Crotalaria Retusa. I
The Structure of Monocrotaline, the Alkaloid in Crotalaria Spectabilis and Crotalaria Retusa. I
复制标题
野百合碱的结构，野百合碱是猪屎豆和猪屎豆中的生物碱。
DOI：
10.1021/ja01265a073
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发表时间：
1939
影响因子：
15
通讯作者：
E. Rogers
中科院分区：
文献类型：
--
作者：
R. Adams;E. Rogers
我们在“氢键”区域研究了普通和氘代乙酸、苯甲酸和丙酸的红外吸收光谱，并根据其结构解释了结果。同样，我们还研究和讨论了二乙基丙二酸和壬二酸的吸收。二苯甲酰甲烷（和相关分子）的红外吸收测量表明，二苯甲酰甲烷经历烯醇化，然后形成氢键。
The infrared absorption spectra for ordinary and deuterated acetic, benzoic and propionic acid have been investigated in the “hydrogen bond’’region and the results interpreted on the basis of their structures. Likewise the absorption for diethylmalonic and azelaic acids has been studied and discussed. Infrared absorption measurements for dibenzoylmethane (and related molecules) suggest that dibenzoylmethane undergoes enolization followed by hydrogen bonding.