Plasma-Induced Free Radicals of Polycrystalline myo-Inositol Studied by Electron Spin Resonance. : Orbital Rehybridization-Induced Effect of Hydroxylalkyl Radicals on Their Reactivities in Crystalline State.
Plasma-Induced Free Radicals of Polycrystalline myo-Inositol Studied by Electron Spin Resonance. : Orbital Rehybridization-Induced Effect of Hydroxylalkyl Radicals on Their Reactivities in Crystalline State.
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通过电子自旋共振研究等离子体诱导的多晶肌醇自由基。
DOI：
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发表时间：
1992
期刊：
影响因子：
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通讯作者：
A. Noguchi
中科院分区：
文献类型：
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作者：
M. Kuzuya;N. Noda;S. Kondo;K. Washino;A. Noguchi
我们报告了第一个详细的 ESR 研究，研究了通过等离子体辐射和温度退火形成的粉末状肌醇中等离子体诱导的碳水化合物自由基。基于 ESR 动力学与系统计算机模拟相结合，发现等离子体辐射通过氢消除在所有四个可能的位点产生羟烷基自由基，并优先在 C2 和 C5 处形成
We report the first detailed ESR study of plasma-induced carbohydrate radicals in powdered myo-inositol formed by plasma irradiation followed by temperature annealing. On basis of the ESR kinetics coupled with the systematic computer simulations, it was found that plasma irradiation produced the hydroxylalkyl radicals at all four possible sites by hydrogen elimination with a preferential formation at C2 and C5