Lycopladine H, a novel alkaloid with fused-tetracyclic skeleton from Lycopodium complanatum
Lycopladine H, a novel alkaloid with fused-tetracyclic skeleton from Lycopodium complanatum
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DOI：
10.1016/j.tetlet.2009.09.035
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发表时间：
2009-11-25
影响因子：
1.8
通讯作者：
Kobayashi, Jun'chi
中科院分区：
文献类型：
--
作者：
Ishiuchi, Kan'ichiro;Kubota, Takaaki;Kobayashi, Jun'chi
从石松藓中分离到一种新的石松属生物碱——石松碱H(1)，它具有一个偶氮烷环与一个[2.2.2]-双环辛烷环和一个3-胡椒酮环组成的融合四环环体系。I的结构和相对立体化学在光谱数据的基础上被阐明(C) 2009 Elsevier Ltd All rights reserved
A novel Lycopodium alkaloid, lycopladine H (1), with a fused-tetracyclic ring system consisting of an azocane ring connected to a [2.2.2]-bicyclooctane ring and a 3-piperidone ring, was isolated from the club moss lycopodium complanatum. The structure and relative stereochemistry of I were elucidated on the basis of spectroscopic data (C) 2009 Elsevier Ltd All rights reserved