Synthesis and characterization of (tetramethylethylenediamine)(9,10-phenanthrenequinone)(9,10-phenanthrenediolato)copper(II), a copper complex containing mixed-charge 9,10-phenanthrenequinone ligands
Synthesis and characterization of (tetramethylethylenediamine)(9,10-phenanthrenequinone)(9,10-phenanthrenediolato)copper(II), a copper complex containing mixed-charge 9,10-phenanthrenequinone ligands
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(四甲基乙二胺)(9,10-菲醌)(9,10-菲二醇)铜(II)（一种含有混合电荷9,10-菲醌配体的铜配合物）的合成和表征
DOI：
10.1021/ic00032a018
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发表时间：
1992
期刊：
影响因子：
--
通讯作者：
C. Pierpont
中科院分区：
文献类型：
--
作者：
G. Speier;S. Tisza;A. Rockenbauer;S. Boone;C. Pierpont
(四甲基乙二胺)(9,10-菲醌)(9,10-菲二醇)铜(II)，Cu(TMEDA)(PhenCat)(PhenBQ)，是通过用含有TMEDA和9,10-菲醌的溶液处理铜金属来制备的。单斜晶系、空间群 P2 1 /n 中的复杂形式的深绿色晶体，晶胞尺寸为 a=14.331 (3) A、b=11.079 (3) A、c=18.471 (3) A、β=101.84 (3) o 、V=2870 (1) A 3 和 Z=4
(Tetramethylethylenediamine)(9,10-phenanthrenequinone)(9,10-phenanthrenediolato)copper(II), Cu(TMEDA)(PhenCat)(PhenBQ), has been prepared by treating copper metal with a solution containing TMEDA and 9,10-phenanthrenequinone. Dark green crystals of the complex form in the monoclinic crystal system, space group P2 1 /n, in a unit cell of dimensions a=14.331 (3) A, b=11.079 (3) A, c=18.471 (3) A, β=101.84 (3) o , V=2870 (1) A 3 , and Z=4