TAML Oxidant Activators: A New Approach to the Activation of Hydrogen Peroxide for Environmentally Significant Problems
TAML Oxidant Activators: A New Approach to the Activation of Hydrogen Peroxide for Environmentally Significant Problems
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DOI：
10.1002/chin.200249239
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发表时间：
2002-12
期刊：
影响因子：
--
通讯作者：
T. J. Collins
中科院分区：
文献类型：
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作者：
T. J. Collins
在绿色氧化化学研究所，我们通过迭代设计过程开发具有有效寿命的氧化催化剂，其中氧化敏感配基被识别和替换。该工艺使催化剂在氧化和水解降解方面的稳定性大大提高。本文所述的铁催化剂可以完全由生物化学上的共同元素组成。它们是许多技术领域高效和选择性的过氧化物活化剂。它们是水溶性的，在很宽的pH范围内，少量（纳摩尔到低微摩尔）就有效。概述了各种绿色化学的应用。
In the Institute for Green Oxidation Chemistry, we develop oxidation catalysts with useful lifetimes via an iterative design process in which oxidation-sensitive ligand groups are identified and replaced. The process has led to catalysts with greatly enhanced stability toward oxidative and hydrolytic degradation. The iron catalysts described herein can be comprised exclusively of biochemically common elements. They are efficient and selective peroxide activators for many areas of technology. They are water-soluble and are effective in minute quantities (nanomolar to low micromolar) over a broad pH range. Various green chemistry applications are sketched.