RAMAN-SPECTROSCOPY OF A COAL LIQUID SHOWS THAT FLUORESCENCE INTERFERENCE IS MINIMIZED WITH ULTRAVIOLET EXCITATION
RAMAN-SPECTROSCOPY OF A COAL LIQUID SHOWS THAT FLUORESCENCE INTERFERENCE IS MINIMIZED WITH ULTRAVIOLET EXCITATION
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DOI：
10.1126/science.6740313
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发表时间：
1984-01-01
期刊：
影响因子：
56.9
通讯作者：
JOHNSON, CR
中科院分区：
文献类型：
--
作者：
ASHER, SA;JOHNSON, CR
首次报道了煤液的紫外共振拉曼光谱测量。光谱详细说明了许多多环芳烃的存在，其环系类似于萘、荧烯、菲、芘和三苯的环系。这一高度复杂的样品的紫外共振拉曼测量表明，荧光没有明显的干扰。无荧光干扰和高选择性表明，紫外共振拉曼光谱是表征高度复杂的样品和混合物的一种强有力的新技术。
The first ultraviolet resonance Raman measurements of a coal liquid are reported. The spectra detail the presence of numerous polycyclic aromatic hydrocarbons with ring systems similar to those of naphthalene, fluorene, phenanthrene, pyrene, and triphenylene. The ultraviolet resonance Raman measurements of this highly complex sample show no significant interference from fluorescence. The lack of fluorescence interference and the high selectivity indicate that ultraviolet resonance Raman spectroscopy is a powerful new technique for characterizing highly complex samples and mixtures.