The site-selective molecular recognition of ternary architectures by using supramolecular nanoporous networks at a liquid-solid interface.

The site-selective molecular recognition of ternary architectures by using supramolecular nanoporous networks at a liquid-solid interface.
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DOI:
10.1002/asia.200900439
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发表时间:
2010-04
期刊:
Chemistry, an Asian journal
影响因子:
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通讯作者:
Yongtao Shen;Min Li;Yuanyuan Guo;K. Deng;Q. Zeng;Chen Wang
Yongtao Shen;Min Li;Yuanyuan Guo;K. Deng;Q. Zeng;Chen Wang
中科院分区:
其他
文献类型:
--
作者:
Yongtao Shen;Min Li;Yuanyuan Guo;K. Deng;Q. Zeng;Chen Wang

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超分子网络不仅为客体分子的包合提供了空穴,而且还能与客体分子发生积极的相互作用。共吸附的微粒通过货车范德华力和氢键相互作用。客体和主体物种之间的弱分子间相互作用可以影响组装结构,例如,通过引起主体框架的晶格几何形状的变化。
The supramolecular networks not only pro-vide cavities for the inclusion of guest molecules, but canalso actively interact with guest molecules. Coadsorbed spe-cies typically interact through van der Waals interactionsand hydrogen bonds. The weak intermolecular interactionsbetween guest and host species can affect assembly struc-tures, for instance, by causing variations in the lattice geo-metries of the host frameworks.