Infrared/visible/ultraviolet spectroscopic detection of one-electron- and two-electron-reduction products of fac-(4-benzoylpyridine)tricarbonylchlororhenium
Infrared/visible/ultraviolet spectroscopic detection of one-electron- and two-electron-reduction products of fac-(4-benzoylpyridine)tricarbonylchlororhenium
复制标题
fac-(4-苯甲酰吡啶)三羰基氯铼的一电子和二电子还原产物的红外/可见/紫外光谱检测
DOI：
10.1021/ic00296a051
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发表时间：
1988
影响因子：
4.6
通讯作者：
M. Wrighton
中科院分区：
文献类型：
--
作者：
C. Shu;M. Wrighton
报告了 (fac-ClRe(CO)/sub 3/(4bzpy)/sub 2/) (4bzpy = 4-苯甲酰吡啶) 的光谱化学研究结果，涉及络合物一电子和二电子还原产物的性质。比较了一电子和二电子还原产物的红外和紫外/可见光谱。获得的光谱和电化学数据与还原的金属络合物的电子位于 4bzpy 配体上的结论一致一致。 14 条参考文献、2 张图、1 个标签。
The results of a spectrochemical investigation of (fac-ClRe(CO)/sub 3/(4bzpy)/sub 2/) (4bzpy = 4-benzoylpyridine) concerning the nature of the products from one- and two-electron reduction of the complex are reported. The ir and uv/visible spectra of the one- and two-electron reduction products are compared. The spectral and electrochemical data obtained are uniformly consistent with the conclusion that the reduced metal complex has the electron(s) localized on the 4bzpy ligand(s). 14 refs., 2 figs., 1 tab.