Conformational Change of an Amylose Derivative in Chiral Solvents: Amylose Tris(n-butylcarbamate) in Ethyl Lactates
Conformational Change of an Amylose Derivative in Chiral Solvents: Amylose Tris(n-butylcarbamate) in Ethyl Lactates
复制标题
直链淀粉衍生物在手性溶剂中的构象变化：乳酸乙酯中的直链淀粉三（正丁基氨基甲酸酯）
DOI：
10.1039/c1py00432h
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
Takahiro Sato
中科院分区：
文献类型：
--
作者：
9.Shota Arakawa;Ken Terao;Shinichi Kitamura;Takahiro Sato
The z-average radius of gyration, the particle scattering function and the intrinsic viscosity have been determined for amylose tris(n-butylcarbamate) (ATBC) in D-, DL- and L-ethyl lactates, all at 25 °C, by light and small-angle X-ray scattering and viscometry as functions of the weight-average molecular weight ranging from 1.7 × 104 to 1.7 × 106 to investigate the chiral solvent dependence of the helical conformation of the amylose derivative. The data were analyzed in terms of the wormlike chain model to determine the Kuhn segment length λ−1 (the stiffness parameter) and the helix pitch per residue h. The λ−1 value of 49 nm in D-EL is 52% larger than 32 nm in L-ethyl lactate, an unmistakable chiral solvent effect to the helical conformation of the amylose derivative, and the relation between h and λ−1 is consistent with that obtained previously in nine different solvents [Polymer, 2010, 51, 4243]. The content of intramolecularly hydrogen bonding CO groups in D-ethyl lactate is estimated to be 15% more than that in L-ethyl lactate, confirmed by heats of dilution for ethyl lactate solutions of ATBC estimated by isothermal titration calorimetry.
