Synthesis, Structure, Photophysics, and Excited‐State Redox Properties of the Novel Luminescent Tetranuclear Acetylidocopper(I) Complex [Cu4(μ‐dppm)4(μ4‐η1,η2‐CC‐)](BF4)2
Synthesis, Structure, Photophysics, and Excited‐State Redox Properties of the Novel Luminescent Tetranuclear Acetylidocopper(I) Complex [Cu4(μ‐dppm)4(μ4‐η1,η2‐CC‐)](BF4)2
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DOI：
10.1002/anie.199611001
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发表时间：
1996-06
影响因子：
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通讯作者：
V. Yam;W. K. Fung;K. Cheung
中科院分区：
文献类型：
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作者：
V. Yam;W. K. Fung;K. Cheung
在激发态的强还原能力只是四核铜（I）配合物1的特征之一。它含有一个乙炔基二价阴离子，以η 1和η 2键模式桥接四个铜原子，并表现出长寿命的发光。结构的中心框架如右图所示。
A strong reducing power in the excited state is just one of the features of the tetranuclear copper(I) complex 1. It contains an acetylide dianion bridging four copper atoms in both η 1 and η 2 bonding modes and exhibits long-lived luminescence. The central framework of the structure is shown on the right.