Synthesis, Characterization, and Magnetic Properties of Two Transition Metal Coordination Polymers Based on 2,5-Furandicarboxylic Acid and N-Donor Ligands
Synthesis, Characterization, and Magnetic Properties of Two Transition Metal Coordination Polymers Based on 2,5-Furandicarboxylic Acid and N-Donor Ligands
复制标题
DOI：
10.1007/s10904-016-0429-0
复制
发表时间：
2016-08
影响因子：
4
通讯作者：
D. Ma;Peng Hu;L. Qin;Jingjing Yan;W. Lin;Wanqiu Ding;Husheng Lu;D. Lin;H. Sakiyama;
中科院分区：
文献类型：
--
作者：
D. Ma;Peng Hu;L. Qin;Jingjing Yan;W. Lin;Wanqiu Ding;Husheng Lu;D. Lin;H. Sakiyama;
合成了两个新的过渡金属配位聚合物[Cu（fdc）（dmbpy）（H2O）]n（1）{[Ni 2（fdc）2（bipy）2（H2O）4]·（H2O）2}n（2）（FDCA = 2，5-呋喃二甲酸，DMBPY = 3，3 ′-二甲基-4，4 ′-联吡啶，bipy = 4，4 ′-联吡啶）在相同的反应条件下进行了合成（H2O，pH 7-8，和130 °C）和结构表征。1是梯形链，而2显示二维（4，4）网络。1和2都通过氢键进一步连接成3D结构。此外，还对1和2的磁性进行了研究。
Two new transition metal-based coordination polymers, [Cu(fdc)(dmbpy)(H2O)]n(1) {[Ni2(fdc)2(bipy)2(H2O)4]·(H2O)2}n(2) (fdca = 2,5-furandicarboxylic acid, dmbpy = 3,3′-dimethyl-4,4′-bipyridine, bipy = 4,4′-bipyridine) have been synthesized under the same reaction conditions (H2O, pH 7–8, and 130 °C) and were structurally characterized.1is a ladder chain, whereas2shows a 2D (4,4) network. Both1and2are further connected into 3D structures through hydrogen bonds. Furthermore, the magnetic properties of1and2are also investigated.