Preparation of Purified KHSO5·H2O and nBu4NHSO5 from Oxone by Simple and Efficient Methods
Preparation of Purified KHSO5·H2O and nBu4NHSO5 from Oxone by Simple and Efficient Methods
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DOI：
10.1002/1099-0690(200210)2002:20
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发表时间：
2002-10
影响因子：
2.8
通讯作者：
B. Travis;Benjamin P. Ciaramitaro;B. Borhan
中科院分区：
文献类型：
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作者：
B. Travis;Benjamin P. Ciaramitaro;B. Borhan
人们对环境友好型氧化剂 Oxone 的各种盐形式的化学性质进行了研究。除了分析纯 KHSO5·H2O 和 nBu4NHSO5（该氧化剂的可溶形式）制备方面的进展外，我们还研究了一些使用 Oxone 作为氧化剂的已知氧化化学。我们的结果表明，使用纯化的试剂使这些反应更容易进行后处理并适合大规模合成，因为反应中盐的量已大大减少。 （© Wiley-VCH Verlag GmbH，69451 魏因海姆，德国，2002 年）
The chemistry of various salt forms of Oxone, an environmentally friendly oxidant, has been investigated. In addition to advances in the preparation of analytically pure KHSO5·H2O and nBu4NHSO5, a soluble form of this oxidant, we have also studied some of the known oxidative chemistry that utilizes Oxone as the oxidant. Our results indicate that utilizing purified reagents makes these reactions easier to workup and amenable to large scale synthesis because the amount of salt in the reaction has been greatly reduced. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)