Syntheses, structures and magnetic properties of two-dimensional chiral coordination polymers based on a tetradentate chiral ligand
Syntheses, structures and magnetic properties of two-dimensional chiral coordination polymers based on a tetradentate chiral ligand
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DOI：
10.1039/c3nj01128c
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发表时间：
2014-04
影响因子：
3.3
通讯作者：
Takuya Shiga;Mayumi Takeo;F. Iijima;Graham N. Newton;H. Oshio
中科院分区：
文献类型：
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作者：
Takuya Shiga;Mayumi Takeo;F. Iijima;Graham N. Newton;H. Oshio
以MCl2·6H2O、S-pabn和K4[Mo(CN)8]为原料，合成了两种具有二维网络结构的手性配位聚合物Δ-[MII(S-pabn)]2[MoIV(CN)8]·3H2O (M = Cu和Co， S-pabn = (S)-N2,N2 ' -双（吡啶-2-甲基-1,1 ' -联萘-2,2 ' -二胺）。Cu（II）或Co（II）中心的未配对电子使化合物表现出顺磁性。
Two chiral coordination polymers, Δ-[MII(S-pabn)]2[MoIV(CN)8]·3H2O (M = Cu and Co, S-pabn = (S)-N2,N2′-bis(pyridin-2-ylmethyl-1,1′-binaphthyl-2,2′-diamine)), with two-dimensional network structures, were synthesized by the reaction of MCl2·6H2O, S-pabn and K4[Mo(CN)8]. The compounds show paramagnetic behavior originating from the unpaired electrons of the Cu(II) or Co(II) centers.