Fluorine-Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions.
Fluorine-Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions.
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DOI：
10.1002/anie.201502624
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发表时间：
2015-07
影响因子：
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通讯作者：
Thomas Vent‐Schmidt;Felix Brosi;J. Metzger;T. Schlöder;Xuefeng Wang;L. Andrews;Carsten Müller;H. Beckers;S. Riedel
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文献类型：
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作者：
Thomas Vent‐Schmidt;Felix Brosi;J. Metzger;T. Schlöder;Xuefeng Wang;L. Andrews;Carsten Müller;H. Beckers;S. Riedel
用基质分离光谱和量子化学方法研究了多氟离子。在低温条件下，首次在850 cm（-1）的氖基质中观察到较高的多氟阴离子[F5]（-）。此外，还报道了氖中Cs(+) [F3]（-）配合物的新能带。
Polyfluoride anions have been investigated by matrix-isolation spectroscopy and quantum-chemical methods. For the first time the higher polyfluoride anion [F5 ](-) has been observed under cryogenic conditions in neon matrices at 850 cm(-1) . In addition, a new band for the Cs(+) [F3 ](-) complex in neon is reported.