The role of weak interactions in controlling the mode of interpenetration in hybrid ultramicroporous materials
The role of weak interactions in controlling the mode of interpenetration in hybrid ultramicroporous materials
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DOI：
10.1039/c6cc10217d
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发表时间：
2017-04-11
影响因子：
4.9
通讯作者：
Zaworotko, Michael J.
中科院分区：
文献类型：
--
作者：
Bajpai, Alankriti;Lusi, Matteo;Zaworotko, Michael J.
发现联吡啶连接基配体中的芳香核影响柱撑正方形网格网络形成的杂化超微孔材料中的2倍互穿模式。晶体结构的分析表明，在相邻的网络中的连接器之间的连接器的构象和弱相互作用可能解释这一现象。
The aromatic core in dipyridyl linker ligands is found to impact the mode of 2-fold interpenetration in hybrid ultramicroporous materials formed by pillared square grid networks. An analysis of the crystal structures suggests that linker conformation and weak interactions between the linkers in adjacent networks might explain this phenomenon.