Preparation, structure, and properties of pseudotetrahedral, D2d complexes of copper(II), nickel(II), cobalt(II), copper(I), and zinc(II) with the geometrically constraining bidentate ligand 2,2'-bis(2-imidazolyl)biphenyl. Examination of electron self-exchange for the Cu(I)/Cu(II) pair
Preparation, structure, and properties of pseudotetrahedral, D2d complexes of copper(II), nickel(II), cobalt(II), copper(I), and zinc(II) with the geometrically constraining bidentate ligand 2,2'-bis(2-imidazolyl)biphenyl. Examination of electron self-exchange for the Cu(I)/Cu(II) pair
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具有几何约束二齿配体 2,2-bis( 的铜 (II)、镍 (II)、钴 (II)、铜 (I) 和锌 (II) 的伪四面体 D2d 配合物的制备、结构和性质
DOI：
10.1021/ja00165a032
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发表时间：
1990
影响因子：
15
通讯作者：
H. Schugar
中科院分区：
文献类型：
--
作者：
S. Knapp;T. Keenan;Xiaohua Zhang;R. Fikar;J. Potenza;H. Schugar
合成了双齿配体2，2‘-双(2-咪唑基)联苯(3=L)，并用于合成高氯酸盐配合物。X-射线结构分析表明，MN(Imh)4生色团为伪四面体，每个生色团都具有近似的二维点对称性。配体3专家对这类络合物的配位球进行了前所未有的几何控制
The bidentate ligand 2,2'-bis(2-imidazolyl)biphenyl (3=L) has been synthesized and used to prepare perchlorate complexes. X-ray structure analysis reveals pseudotetrahedral, MN(imH) 4 chromophores, each with approximate D 2d point symmetry. The ligand 3 experts an unprecedented degree of geometric control of the coordination spheres for complexes of this type