Alternative syntheses of the new D2d symmetric tetramethyl tricyclo-[3.3.0.03,7]octane-1,3,5,7-tetracarboxylate

Alternative syntheses of the new D2d symmetric tetramethyl tricyclo-[3.3.0.03,7]octane-1,3,5,7-tetracarboxylate
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DOI:
10.1021/jo035062x
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发表时间:
2003-10-31
影响因子:
3.6
通讯作者:
Vázquez, S
Vázquez, S
中科院分区:
化学2区
文献类型:
--
作者:
Ayats, C;Camps, P;Vázquez, S

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从已知的 3,7-二氧代-顺式-双环[3.3.0]辛烷-1,5-二甲酸二甲酯合成新型 D-2d 对称四甲基三环[3.3.0.0(3,7)]辛烷-1,3,5,7-四甲酸描述了1,5-(2,2'-亚联苯基)顺式-双环[3.3.0]辛烷-3,7-二酮。
Two alternative syntheses of the new D-2d symmetric tetramethyl tricyclo [3.3.0.0(3,7)] octane-1,3,5,7-tetra-carboxylate from the known dimethyl 3,7-dioxo-cis-bicyclo[3.3.0]octane-1,5-dicarboxylate and 1,5-(2,2'-biphenylene)cis-bicyclo[3.3.0]octane-3,7-dione are described.