Polymorphism of 1,3,5-trinitrobenzene induced by a trisindane additive.

Polymorphism of 1,3,5-trinitrobenzene induced by a trisindane additive.
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DOI:
10.1002/anie.200352253
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发表时间:
2004-02
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通讯作者:
P. Thallapally;R. K. Jetti;A. K. Katz;H. L. Carrell;Kuldeep Singh;K. Lahiri;S. Kotha;R. Boese;G. Desiraju
P. Thallapally;R. K. Jetti;A. K. Katz;H. L. Carrell;Kuldeep Singh;K. Lahiri;S. Kotha;R. Boese;G. Desiraju
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文献类型:
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作者:
P. Thallapally;R. K. Jetti;A. K. Katz;H. L. Carrell;Kuldeep Singh;K. Lahiri;S. Kotha;R. Boese;G. Desiraju

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最稳定的不一定是最容易获得的!本文报道了具有120年历史的合成三硝基苯的两种新的稳定晶型。这些难以捉摸的形式是通过使用添加剂三辛烷获得的,三辛烷可以在结晶实验中充当模拟物。
The most stable is not necessarily the most easy to obtain! Two new stable crystal forms of the 120 year old compound sym-trinitrobenzene are reported. These elusive forms have been obtained by the use of an additive, trisindane, that can act as a mimic in the crystallization experiment.