Acid-Base Reactions in Non-dissociating Solvents. Acetic Acid and Triethylamine in Carbon Tetrachloride and Chloroform
Acid-Base Reactions in Non-dissociating Solvents. Acetic Acid and Triethylamine in Carbon Tetrachloride and Chloroform
复制标题
非离解溶剂中的酸碱反应。
DOI：
10.1021/ja01622a009
复制
发表时间：
1954
期刊：
影响因子：
--
通讯作者：
G. M. Barrow
中科院分区：
文献类型：
--
作者：
E. Yerger;G. M. Barrow
用红外光谱法研究了乙酸和二乙胺在四氯化碳和氯仿中的反应。从观测到的光谱变化中推导出了变化对产物的结构。这些都是在其预期的稳定性方面进行讨论。在三乙胺-乙酸系统中，与氯仿分子的相互作用极大地改变了离子对的电子结构。几个反应的平衡常数，并与以前的结果进行了比较。
The reactions between acetic acid and diethylamine in carbon tetrachloride and chloroform were studied by infrared spectroscopy. Structures for the variousion-pair products havebeen deduced from the observed spectral changes. These are discussed in terms of their expected stabilities. As in the triethylamine-acetic acid system, interaction with chloroform molecules greatly alters the electronic structure of the ion pairs. Equilibrium constants were determined for several of the reactions and were compared with previous results.