The crystal azimuth dependence of the angular distribution of the desorption flux of carbon dioxide produced on palladium (110) surfaces
The crystal azimuth dependence of the angular distribution of the desorption flux of carbon dioxide produced on palladium (110) surfaces
复制标题
钯（110）表面产生的二氧化碳解吸通量角分布的晶体方位角依赖性
DOI：
10.1063/1.457526
复制
发表时间：
1989
影响因子：
4.4
通讯作者：
T. Matsushima
中科院分区：
文献类型：
--
作者：
T. Matsushima
采用LEED和角分辨热解吸技术研究了CO(a)和O(a)在Pd（110）上的反应。在160 ~ 460 K范围内，加热涂层产生5个CO2形成峰。它们的角度分布是不同的。随着叠片层密度的增加，其分布变得更加明显，并表现出与晶体方位的依赖关系。讨论了各向异性角分布与反应部位周围结构的关系。
The reaction of CO(a) and O(a) on Pd(110) was studied with LEED and angle‐resolved thermal desorption. Heating the coadlayer produces five peaks in the CO2 formation in the range of 160 to 460 K. The angular distribution of each is different. The distribution becomes sharper as the density of the coadlayer is increased, and it shows the dependence on the crystal azimuth. The correlation between the anisotropic angular distribution and the structure around the reaction site is discussed.