Mono- and Dihydroxylated Symmetrical Octamethylcucurbiturils and Allylated Derivatives.
Mono- and Dihydroxylated Symmetrical Octamethylcucurbiturils and Allylated Derivatives.
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DOI:
10.1021/acs.orglett.6b02789
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发表时间:
2016-10
期刊:
影响因子:
5.2
通讯作者:
Fang-Fang Shen-Fang;Kai Chen;Yunqian Zhang;Qian-jiang Zhu;Z. Tao;H. Cong
中科院分区:
文献类型:
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作者:
Fang-Fang Shen-Fang;Kai Chen;Yunqian Zhang;Qian-jiang Zhu;Z. Tao;H. Cong
Mono- and dihydroxylated symmetrical octamethylcucurbit[6]urils {(OH)OMeQ[6] and (OH)2OMeQ[6]} were prepared using a photochemical method to introduce limited alcohol group(s) directly to the parent symmetrical octamethylcucurbit[6]uril (OMeQ[6]), and the resulting compounds were verified by 1H NMR, Xevo Q-TOF MS, and X-ray crystallography. Further chemical modification of mono- and dihydroxylated OMeQ[6] was also performed.