HIGHLY EFFICIENT APPROACH TO (+)-GRANDISOL VIA A DIASTEREOSELECTIVE [2+2] PHOTOCYCLOADDITION TO 2(5H)-FURANONES
HIGHLY EFFICIENT APPROACH TO (+)-GRANDISOL VIA A DIASTEREOSELECTIVE [2+2] PHOTOCYCLOADDITION TO 2(5H)-FURANONES
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DOI：
10.1016/s0040-4039(00)60151-x
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发表时间：
1993-11-12
影响因子：
1.8
通讯作者：
FONT, J
中科院分区：
文献类型：
--
作者：
ALIBES, R;BOURDELANDE, JL;FONT, J
通过乙烯与一种容易获得的纯手性丁烯二醇的非对映选择性光环加成反应，描述了一种制备（+）和（-）-grandisol的新方法。得到光学纯的中间体。
A new approach to (+) and (-)-grandisol is described through a diastereoselective photocycloaddition of ethylene to an easily available homochiral butenolide. Optically pure intermediates are obtained.