Morphology, rheological and crystallization behavior in non-covalently functionalized carbon nanotube reinforced poly(butylene succinate) nanocomposites with low percolation threshold
Morphology, rheological and crystallization behavior in non-covalently functionalized carbon nanotube reinforced poly(butylene succinate) nanocomposites with low percolation threshold
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具有低渗滤阈值的非共价功能化碳纳米管增强聚丁二酸丁二醇酯纳米复合材料的形态、流变和结晶行为
DOI：
10.1016/j.polymertesting.2016.01.003
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发表时间：
2016-04
期刊：
影响因子：
5.1
通讯作者：
Zeng Jian-Bing
中科院分区：
文献类型：
--
作者：
Zeng Run-Tao;Hu Wei;Wang Ming;Zhang Shui-Dong;Zeng Jian-Bing
Multi-walled carbon nanotubes (CNTs) were non-covalently functionalized by surface wrapping of poly(sodium 4-styrenesulfonate) (PSS) with the aid of ultrasound. The functionalized CNTs were incorporated into poly(butylene succinate) (PBS) through solution coagulation to fabricate CNTs filled PBS nanocomposites. The morphologies of the PBS/CNT nanocomposites were studied by scanning electron microscope (SEM) and transmission electron microscope (TEM), and the effect of loading of functionalized CNT on the rheological behavior, electrical conductivity and mechanical properties of the nanocomposites was investigated systemically. SEM observation indicates that functionalized CNTs dispersed in PBS matrix without obvious aggregation and showed good interfacial adhesion with the PBS phase. TEM observation reveals that a CNT network was formed when the loading of CNTs increased from 0.1 to 0.3 wt%. Rheological investigation indicates the formation of a CNT network with a percolation threshold of only 0.3 wt%. Significant improvement in electrical conductivity occurred at CNT loading of 0.3 wt%, with the value of electrical conductivity increasing by six orders of magnitude compared to neat PBS. Differential scanning calorimetry indicates that the melt crystallization temperature of PBS was improved by ∼14 °C with addition of only 0.05 wt% functionalized CNTs. Tensile tests indicate that both the yield strength and Young's modulus of PBS were apparently reinforced by incorporation of functionalized CNTs, while the elongation at break was reduced gradually.
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DOI：
10.1002/polb.21728
发表时间：
2009-07
期刊：
Journal of Polymer Science Part B
影响因子：
--
作者：
Y. Shih
通讯作者：
Y. Shih
聚（丁二酸乙二酯）-b-聚（丁二酸丁二酯）多嵌段共聚酯：嵌段长度和组成对物理性能的影响
影响因子：
4.2
作者：
Xu Chang-Lian;Zeng Jian-Bing;Zhu Qun-Ying;Wang Yu-Zhong
通讯作者：
Wang Yu-Zhong
通过离子基团分布调节聚（丁二酸丁二醇酯）离聚物的性能
影响因子：
4.6
作者：
Lv Liang;Wu Fang;Chen Si-Chong;Wang Yu-Zhong;Zeng Jian-Bing
通讯作者：
Zeng Jian-Bing
影响因子：
15.1
作者：
Zhao-yang Zhang;Xuecheng Xu
通讯作者：
Zhao-yang Zhang;Xuecheng Xu
影响因子：
5.1
作者：
Kueseng, Pattana;Sae-oui, Pongdhorn;Rattanasom, Nittaya
通讯作者：
Rattanasom, Nittaya