Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert‐butyl hydroperoxide as oxidant
Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert‐butyl hydroperoxide as oxidant
复制标题
DOI：
10.1002/aoc.3281
复制
发表时间：
2015-04
影响因子：
3.9
通讯作者：
Abudureheman Wusiman;Chong-Dao Lu
中科院分区：
文献类型：
--
作者：
Abudureheman Wusiman;Chong-Dao Lu
结果表明，负载0.1 mol%的负载下，四氨基酸二钠配合物Rh2(Msip)4能有效催化活性仲醇的氧化。在这种方法中，我们使用便宜的氧化剂T-HYDRO®（70 wt%的水过氧化叔丁基）在温和的水条件下将各种苯基、烯丙基和丙炔醇氧化为相应的羰基化合物。版权所有©2015 John Wiley & Sons， Ltd
We show that the dirhodium(II) tetraamidinate complex Rh2(Msip)4 efficiently catalyzes the oxidation of activated secondary alcohols at only 0.1 mol% loading. In this approach, we oxidized various benzylic, allylic and propargylic alcohols to the corresponding carbonyl compounds under mild aqueous conditions using the inexpensive oxidant T-HYDRO® (70 wt% aqueous tert-butyl hydroperoxide). Copyright © 2015 John Wiley & Sons, Ltd.