Combinatorial Molecular Imprinting for Formation of Atrazine Decomposing Polymers
Combinatorial Molecular Imprinting for Formation of Atrazine Decomposing Polymers
复制标题
用于形成莠去津分解聚合物的组合分子印迹
DOI：
10.1246/cl.2001.530
复制
发表时间：
2001
影响因子：
1.6
通讯作者：
T. Mukawa
中科院分区：
文献类型：
--
作者：
T. Takeuchi;Daigo Fukuma;J. Matsui;T. Mukawa
通过分子印迹制备了能够选择性分解莠去津的合成聚合物。采用组合方法，使用自动化聚合物制备/评估系统来选择功能单体来构建莠去津分解位点。甲基丙烯酸和甲基丙烯酸2-磺基乙酯的组合使用提供了莠去津分解聚合物，其中莠去津转化为无毒化合物阿特拉通，并且印迹效应增强了催化活性。
Synthetic polymers capable of atrazine-selective decomposition were prepared by molecular imprinting. A combinatorial approach was employed using an automated polymer preparation/evaluation system for the selection of functional monomers to construct the atrazine decomposition sites. Combined use of methacrylic acid and 2-sulfoethyl methacrylate provided atrazine-decomposing polymers in which atrazine was converted to a non-toxic compound atraton and the imprinting effects enhanced the catalytic activity.