Formation of a stable dicarbenoid and an unsaturated C2P2S2 ring from two-electron oxidation of the [C(PPh2S)2]2- dianion.
Formation of a stable dicarbenoid and an unsaturated C2P2S2 ring from two-electron oxidation of the [C(PPh2S)2]2- dianion.
复制标题
通过 [C(PPh2S)2]2- 二价阴离子的双电子氧化形成稳定的二碳烯和不饱和 C2P2S2 环。
作者：
J. Konu;T. Chivers
用碘对 [C(PPh(2)S)(2)](2-) 二价阴离子进行双电子氧化，得到了意想不到的二聚 Li-I 类胡萝卜素 [(Et(2)O)(mu-Li)][(mu(4)-Li){IC(PPh(2)S)(2)}(2)] 和新型不饱和六元 C(2)P(2)S(2) 环的混合物。 [(SPh(2)P)(2)C(2)(PPh(2))(2)S(2)]。
Two-electron oxidation of the [C(PPh(2)S)(2)](2-) dianion with iodine afforded an unexpected mixture of a dimeric Li-I carbenoid [(Et(2)O)(mu-Li)][(mu(4)-Li){IC(PPh(2)S)(2)}(2)] and a novel, unsaturated six-membered C(2)P(2)S(2) ring in [(SPh(2)P)(2)C(2)(PPh(2))(2)S(2)].