Iron-catalysed chemo- and ortho-selective C-H bond functionalization of phenols with alpha-aryl-alpha-diazoacetates

Iron-catalysed chemo- and ortho-selective C-H bond functionalization of phenols with alpha-aryl-alpha-diazoacetates
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铁催化的 α-芳基-α-重氮乙酸酯对苯酚的化学和邻位选择性 C-H 键官能化

DOI:
10.1039/d1qo00276g
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发表时间:
2021
影响因子:
5.4
通讯作者:
Liu Lu
Liu Lu
中科院分区:
化学1区
文献类型:
--
作者:
Yu Zhunzhun;Li Guanghui;Zhang Junliang;Liu Lu

文献摘要

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Herein we present a novel iron-catalyzed chemo- and regio-selective ortho C–H bond functionalization of phenols and naphthols with diazo compounds. In this transformation, an iron porphyrin exhibits specific catalytic activity, and is quite different from the commonly used precious metal catalysts.