Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides
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DOI:
10.1016/j.tetlet.2005.06.109
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发表时间:
2005-08-22
影响因子:
1.8
通讯作者:
Yamaguchi, M
Yamaguchi, M
中科院分区:
化学4区
文献类型:
--
作者:
Arisawa, M;Ono, T;Yamaguchi, M

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在RHH(PPh_3)(4)和1,2-二苯基膦乙烷(Dppe)存在下,二硫化物与二膦盐反应合成了烷基和芳基二硫代膦。该催化剂还促进了由二硫化物和二硒化物合成硫代磷酸盐和硒硫代磷酸盐。(C)2005爱思唯尔有限公司。保留所有权利。
Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh3)(4) and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides. (c) 2005 Elsevier Ltd. All rights reserved.