Colloidal crystal capillary columns - Towards optical chromatography

Colloidal crystal capillary columns - Towards optical chromatography
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DOI:
10.1002/adma.200400020
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发表时间:
2005-02-23
期刊:
影响因子:
29.4
通讯作者:
Mabury, SA
Mabury, SA
中科院分区:
材料科学1区
文献类型:
--
作者:
Kamp, U;Kitaev, V;Mabury, SA

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胶体晶体毛细管柱(C(4)s);由毛细管中压力辅助胶体微球组装(PACMAC)产生的(见封盖)在可见光和近红外光谱范围内显示出高度的光学均匀性,并且能够通过衍射在光谱上区分烷烃。图中为180nm(蓝色)和225nm(绿色)聚苯乙烯微球C(4)s的切片,以及经乙醇浸润后直径为225nm的聚苯乙烯微球C-4(黄色)。
Colloidal crystal capillary columns (C(4)s; see cover) produced by pressure-assisted colloidal-microsphere assembly in capillaries (PACMAC) display a high degree of optical uniformity in the visible and near-IR spectral ranges and are able to spectroscopically differentiate alkanes by diffraction. The Figure shows sections of 180 nm (blue) and 225 nm diameter (green) polystyrene microsphere C(4)s, and the 225 nm diameter polystyrene microsphere C-4 after infiltration with ethanol (yellow).