Group 4 Metallocenes in Bioorganometallic Chemistry
Group 4 Metallocenes in Bioorganometallic Chemistry
复制标题
生物有机金属化学中的第 4 族茂金属
DOI：
10.1002/chin.200724267
复制
发表时间：
2007
期刊：
影响因子：
--
通讯作者：
G. Erker
中科院分区：
文献类型：
--
作者：
G. Erker
Abstract Group 4 metallocene complexes can form adducts or condensation products with a variety of typical biogenic molecules. In this account, examples are presented and discussed for the reactions of zirconocene or titanocene complexes with suitably protected/deprotected carbohydrate derivatives. Some methodological developments are shown for the attachment of aminoacid or peptide derived functional groups at the Cp-rings of the Group 4 bent metallocenes. Eventually, the reactions of methylzirconocene- and methyltitanocene cations with a series of short oligopeptides are discussed that lead to the formation of primary κO-adducts followed by O,N,O-chelate complex formation with methane evolution. The dynamic features of some such systems are discussed.
影响因子：
2.9
作者：
Guo, ML;Sun, HZ;Sadler, PJ
通讯作者：
Sadler, PJ