Physicochemical Studies on Microemulsions. 7. Dynamics of Percolation and Energetics of Clustering in Water/AOT/Isooctane and Water/AOT/Decane w/o Microemulsions in Presence of Hydrotopes (Sodium Salicylate, α-Naphthol, β-Naphthol, Resorcinol, Catechol, Hydroquinone, Pyrogallol and Urea) and Bile Sa
Physicochemical Studies on Microemulsions. 7. Dynamics of Percolation and Energetics of Clustering in Water/AOT/Isooctane and Water/AOT/Decane w/o Microemulsions in Presence of Hydrotopes (Sodium Salicylate, α-Naphthol, β-Naphthol, Resorcinol, Catechol, Hydroquinone, Pyrogallol and Urea) and Bile Sa
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DOI：
10.1021/jp0105084
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发表时间：
2001-06
影响因子：
3.3
通讯作者：
S. H. and;S. P. Moulik;Marianne Rodgers;and S. E. Burke;R. Palepu
中科院分区：
文献类型：
--
作者：
S. H. and;S. P. Moulik;Marianne Rodgers;and S. E. Burke;R. Palepu
研究了水/AOT/异辛烷和水/AOT/癸烷两种W/O型微乳液体系在不同[水]/[AOT]摩尔比（ω）下，在水溶助长剂（水杨酸钠、α-萘酚、β-萘酚、间苯二酚、邻苯二酚、对苯二酚、连苯三酚、尿素）和胆盐胆酸钠存在下的温度诱导渗流。结果进行了分析，以量化的阈值逾渗温度，性能的缩放方程，活化能的逾渗过程中，分散的纳米液滴的聚类的热力学。温度和添加剂对液滴尺寸，多分散性，和扩散系数的影响也进行了研究的DLS研究。尝试已取得的相关结果与不同的活动的水溶助长剂。提出了水溶助长剂活性变化的可能机理。
The temperature induced percolation of w/o microemulsions (water/AOT/isooctane and water/AOT/decane) has been studied at different [water]/[AOT] mole ratios (ω), and in the presence of hydrotopes (sodium salicylate, α-naphthol, β-naphthol, resorcinol, catechol, hydroquinone, pyrogallol, urea) and the bile salt sodium cholate. The results have been analyzed to quantify the threshold percolation temperature, performance of the Scaling equation, the activation energy for the percolation process, and the thermodynamics of the clustering of the dispersed nanodroplets. The influence of temperature and additives on the droplet dimension, the polydispersity, and the diffusion coefficient has been also investigated by the DLS studies. An attempt has been made to correlate the results with the differential activities of the hydrotopes. A possible mechanism of the varied activities of the hydrotopes is proposed.