A new generation of aprotic yet Brønsted acidic imidazolium salts: low toxicity, high recyclability and greatly improved activity

A new generation of aprotic yet Brønsted acidic imidazolium salts: low toxicity, high recyclability and greatly improved activity
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DOI:
10.1039/c3gc40975a
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发表时间:
2013-09
期刊:
影响因子:
9.8
通讯作者:
L. Myles;Rohitkumar G. Gore;N. Gathergood;S. Connon
L. Myles;Rohitkumar G. Gore;N. Gathergood;S. Connon
中科院分区:
化学1区
文献类型:
--
作者:
L. Myles;Rohitkumar G. Gore;N. Gathergood;S. Connon

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目前已开发出一种低抗菌毒性的非质子型催化剂,在质子添加剂的存在下可作为Bronsted酸性催化剂。这些催化剂是可回收的,活性大大提高(即可以在低负荷10-50倍的情况下使用),并且比上一代的应用范围更广。
Catalysts which have low antimicrobial toxicity and are aprotic, yet which can act as Bronsted acidic catalysts in the presence of protic additives have been developed. The catalysts are recyclable, considerably more active (i.e. can be used at 10–50 times lower loadings) and of broader scope than their antecedent generation.