NMR-spectroscopic evidence of intermediate-dependent pathways for acetic acid formation from methane and carbon monoxide over a ZnZSM-5 zeolite catalyst.
NMR-spectroscopic evidence of intermediate-dependent pathways for acetic acid formation from methane and carbon monoxide over a ZnZSM-5 zeolite catalyst.
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DOI：
10.1002/anie.201108634
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发表时间：
2012-04
影响因子：
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通讯作者：
Xiumei Wang;Guodong Qi;Jun Xu;Bojie Li;Chao Wang;F. Deng
中科院分区：
文献类型：
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作者：
Xiumei Wang;Guodong Qi;Jun Xu;Bojie Li;Chao Wang;F. Deng
两种方式：开发了一种Zn改性的ZSM-5沸石催化剂，用于甲烷与一氧化碳在温和条件（573-623 K）下直接制备乙酸的反应，并且通过原位固态NMR光谱法明确鉴定了两种不同的依赖于中间体的反应途径用于乙酸的形成。
Two ways: a Zn-modified ZSM-5 zeolite catalyst was developed for the reaction of methane with carbon monoxide to directly produce acetic acid under mild conditions (573-623 K), and two different intermediate-dependent reaction pathways were unambiguously identified for acetic acid formation by in situ solid-state NMR spectroscopy.