The effect of transition metals on the structure of h-BN intercalation compounds

The effect of transition metals on the structure of h-BN intercalation compounds
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过渡金属对h-BN插层化合物结构的影响

DOI:
10.1016/j.jssc.2003.12.038
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发表时间:
2004
影响因子:
3.3
通讯作者:
Ç. Bozkurt
Ç. Bozkurt
中科院分区:
化学3区
文献类型:
--
作者:
E. Budak;Ç. Bozkurt

文献摘要

被引文献

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在本研究中,在各种金属硝酸盐 [M(NO3)x,M=Cr、Mn、Fe、Co、Ni、Cu、Zn 和 Ag] 存在下,通过改进的 O’Connor 方法合成了六方氮化硼 (h-BN)。通过 FTIR、XRF、XRD 和 SEM 技术对复合材料进行了分析。 XRD 结果表明,由于 Cr、Mn、Fe 和 Ag 的插入,层间距发生了变化。 SEM 分析表明,即使在 1320K 的温度下,金属嵌入时晶粒也会生长。
In this study, hexagonal boron nitride (h-BN) were synthesized by the modified O’Connor method in the presence of various metal nitrates [M(NO3)x, M=Cr, Mn, Fe, Co, Ni, Cu, Zn, and Ag]. The composites were analyzed by FTIR, XRF, XRD, and SEM techniques. XRD results indicated a change in the interlayer spacing due to the intercalation of Cr, Mn, Fe and Ag. SEM analyses illustrated the grain growth upon metal intercalation even at a temperature of 1320K.