Electrocatalytic oxidation of amines to nitriles on a TEMPO-modified graphite felt electrode (TEMPO = 2,2,6,6-tetramethylpiperidin-1-yloxyl)
Electrocatalytic oxidation of amines to nitriles on a TEMPO-modified graphite felt electrode (TEMPO = 2,2,6,6-tetramethylpiperidin-1-yloxyl)
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DOI：
10.1002/jccs.199800023
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发表时间：
1998-02-01
影响因子：
1.8
通讯作者：
Bobbitt, JM
中科院分区：
文献类型：
--
作者：
Kashiwagi, Y;Kurashima, F;Bobbitt, JM
在聚丙烯酸修饰的石墨毡电极上，以4-氨基-2，2，6，6-四甲基哌啶-1-氧基为固定剂，成功地实现了胺的高选择性（> 95%）和高电流效率（> 92%）的电催化氧化。
Preparative electrocatalytic oxidation of amines to nitriles was successfully achieved on a poly (acrylic acid)-coated graphite felt electrode immobilizing 4-amino-2,2,6,6-tetramethylpiperidin-1-yloxyl in high selectivity (> 95%) and high current efficiency (> 92%).