Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source.
Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source.
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DOI：
10.1039/c4cc05908e
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发表时间：
2014-10
影响因子：
4.9
通讯作者：
Solène Savourey;G. Lefèvre;J. Berthet;T. Cantat
中科院分区：
文献类型：
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作者：
Solène Savourey;G. Lefèvre;J. Berthet;T. Cantat
提出了一种使用甲酸作为独特的碳和氢源来直接甲基化胺的新方法。基于钌(II)催化剂，N-CH3基团的形成通过有效的甲酰化/转移氢化途径进行。
A novel methodology is presented for the direct methylation of amines, using formic acid as a unique source of carbon and hydrogen. Based on ruthenium(II) catalysts, the formation of the N-CH3 group proceeds via an efficient formylation/transfer hydrogenation pathway.