N-alkyl-4-boronopyridinium salts as thermally stable and reusable amide condensation catalysts

N-alkyl-4-boronopyridinium salts as thermally stable and reusable amide condensation catalysts
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DOI:
10.1021/ol052060l
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发表时间:
2005-10-27
期刊:
影响因子:
5.2
通讯作者:
Yamamoto, H
Yamamoto, H
中科院分区:
化学1区
文献类型:
--
作者:
Maki, T;Ishihara, K;Yamamoto, H

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[图解]N-烷基-4-硼-吡啶盐是高效和可重复使用的催化剂,用于羧酸和胺的等摩尔混合物之间的脱水酰胺缩合反应。N-烷基硼-2-吡啶盐的热稳定顺序为N-烷基-2-硼-吡啶盐
[GRAPHICS]N-Alkyl-4-boronopyridinium salts are highly effective and reusable catalysts for the dehydrative amide condensation reaction between equimolar mixtures of carboxylic acids and amines. N-Alkylboronopyridinium salts are thermally stabilized in the order N-alkyl-2-boronopyridinium salt