Laser induced fluorescence (LIF) of Hg2 and Hg3 via dissociation of HgBr2 at 157 nm

Laser induced fluorescence (LIF) of Hg2 and Hg3 via dissociation of HgBr2 at 157 nm
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通过在 157 nm 处解离 HgBr2 产生 Hg2 和 Hg3 的激光诱导荧光 (LIF)

DOI:
10.1007/bf01437444
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发表时间:
1991
期刊:
Zeitschrift für Physik D Atoms, Molecules and Clusters
影响因子:
--
通讯作者:
A. Cefalas
A. Cefalas
中科院分区:
--
文献类型:
--
作者:
Constantine Skordoulis;E. Sarantopoulou;S. Spyrou;C. Kosmidis;A. Cefalas

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用F2分子激光解离7.88 eV(157.5 nm)的HgBr2,结合汞原子从高激发态跃迁产生的荧光,获得了汞团簇Hg2和Hg3的激光诱导荧光。激发过程包括双光子吸收,分子在15.76 eV总光子能量下解离,随后形成金属团簇。
Laser induced fluorescence of the mercury clusters Hg2and Hg3in the spectral range between 300 nm to 510 nm has been obtained from the dissociation of HgBr2at 7.88 eV (157.5 nm) with an F2molecular laser, together with fluorescence from mercury atomic transitions from highly excited states. The excitation process involves two photon absorption which dissociates the molecule at 15.76 eV total photon energy with the subsequent formation of the metallic clusters.