Cryptand Addition to Polyelectrolytes: A Means of Conductivity Enhancement and a Probe of Ionic Interactions
Cryptand Addition to Polyelectrolytes: A Means of Conductivity Enhancement and a Probe of Ionic Interactions
复制标题
聚电解质中的穴状配体添加：增强电导率的方法和离子相互作用的探索
DOI：
10.1021/ja00113a024
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发表时间：
1995
影响因子：
15
通讯作者：
D. Shriver
中科院分区：
文献类型：
--
作者：
M. Lonergan;M. Ratner;D. Shriver
作为探测单离子导电聚合物电解质中的离子相互作用和增强其导电性的手段，研究了穴状配体4，7，13，16，21，24-六氧杂-1，10-二氮杂双环[8.8. 8]二十六烷（crypt [2.2. 2])研究了聚{{[co-甲氧基聚氧乙烯]丙基}甲基硅氧烷}-FC/ocFC-[4-（3，5-二叔丁基-4-羟基苯基）丁基]甲基硅氧烷}钠盐（1）的电导率。具有和不具有穴状体的两种样品都显示出其电导率的特征VTF温度依赖性（= 0.0001）。
As a means of probing ionic interactions in and enhancing the conductivity of single-ion conducting polymer electrolytes, the effect of the cryptand 4, 7, 13, 16, 21, 24-hexaoxa-1, 10-diazabicyclo [8.8. 8] hexacosane (crypt [2.2. 2]) on the conductivity of the sodium salt of poly {poly {{[co-methoxypoly (oxyethylene)] propyl} methylsiloxane}-fc/ocfc-[4-(3, 5-di-fért-butyl-4-hydroxyphenyl) butyl] methylsiloxane}(1) was studied. Both samples with and without cryptand display the characteristic VTF temperature dependence of their conductivities (=