The Interplay of Quantum Confinement and Hydrogenation in Amorphous Silicon Quantum Dots.

The Interplay of Quantum Confinement and Hydrogenation in Amorphous Silicon Quantum Dots.
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DOI:
10.1002/adma.201503013
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发表时间:
2015-12-22
期刊:
Advanced materials (Deerfield Beach, Fla.)
影响因子:
--
通讯作者:
Mariotti D
Mariotti D
中科院分区:
其他
文献类型:
--
作者:
Askari S;Svrcek V;Maguire P;Mariotti D

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非晶硅量子点(QD)中的氢化对相应的光学性质和能带结构具有显著影响,从而产生具有独特特性的量子限制复合材料。a-Si:H量子点的合成是用大气压等离子体工艺来证明的,该工艺允许精确控制高度化学反应性的非平衡环境,温度远低于Si量子点的结晶温度。
Hydrogenation in amorphous silicon quantum dots (QDs) has a dramatic impact on the corresponding optical properties and band energy structure, leading to a quantum‐confined composite material with unique characteristics. The synthesis of a‐Si:H QDs is demonstrated with an atmospheric‐pressure plasma process, which allows for accurate control of a highly chemically reactive non‐equilibrium environment with temperatures well below the crystallization temperature of Si QDs.