Selective synthesis of two-dimensional semiconductive coordination polymers with silver-sulfur network
Selective synthesis of two-dimensional semiconductive coordination polymers with silver-sulfur network
复制标题
银硫网络二维半导体配位聚合物的选择性合成
DOI：
10.1039/d3ce00106g
复制
发表时间：
2023
期刊：
影响因子：
3.1
通讯作者：
Tanaka Daisuke
中科院分区：
文献类型：
--
作者：
Akiyoshi Ryohei;Saeki Akinori;Ogasawara Kazuyoshi;Yoshikawa Hirofumi;Nakamura Yuiga;Tanaka Daisuke
合成并表征了含硫配位原子的二维Ag（I）配位聚合物[Ag（tzdt）]n（KGF-24）和[Ag（tzdt）（TFA）]n（KGF-25）（Htzdt = 1，3-噻唑烷-2-基，TFA =三氟乙酸盐）.时间分辨的微波电导率测量和第一性原理计算表明，KGF-24和KGF-25表现出电荷迁移沿着它们的（-Ag-S-）n网络。
Two-dimensional Ag(I) coordination polymers containing a sulfur coordination atom, [Ag(tzdt)]n (KGF-24), and [Ag(tzdt)(TFA)]n (KGF-25) (Htzdt = 1,3-thiazolidine-2-thione, TFA = trifluoroacetate), were synthesized and characterized. Time-resolved microwave conductivity measurements and first-principles calculations revealed that KGF-24 and KGF-25 exhibit charge mobility along their (–Ag–S–)n network.