Unswollen Layer of Cross-linked Polyisoprene at the Solid Interface

Unswollen Layer of Cross-linked Polyisoprene at the Solid Interface
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固体界面处交联聚异戊二烯的未溶胀层

DOI:
10.1016/j.polymer.2016.07.047
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发表时间:
2016
期刊:
影响因子:
4.6
通讯作者:
and K. Tanaka
and K. Tanaka
中科院分区:
化学2区
文献类型:
--
作者:
S. Shimomura;M. Inutsuka;N. L. Yamada;and K. Tanaka

文献摘要

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通过镜面中子反射率检查旋涂在己烷中的石英基板上的交联聚异戊二烯 (PI) 薄膜的密度分布。我们在基板界面发现了两层具有不同 PI 密度的层。层的特性根据通常与橡胶材料领域相关的结合橡胶和通常与玻璃材料领域相关的吸附层来讨论。
The density profile in a thin cross-linked polyisoprene (PI) film spin-coated on a quartz substrate inn-hexane was examined by specular neutron reflectivity. We found two layers with different PI densities at the substrate interface. The characteristics of the layers are discussed in terms of bound rubber typically associated with the field of rubber materials and adsorbed layers typically associated with the field of glassy materials.