Cationic Five-Coordinate Bis(guanidinato)silicon(IV) Complexes with SiN4 El Skeletons (El=S, Se): "Heterolytic Activation" of S-S and Se-Se Bonds.
Cationic Five-Coordinate Bis(guanidinato)silicon(IV) Complexes with SiN4 El Skeletons (El=S, Se): "Heterolytic Activation" of S-S and Se-Se Bonds.
复制标题
阳离子五配位双(胍基)硅(IV)与 SiN4 El 骨架(El=S,Se)配合物:S-S 和 Se-Se 键的“异解活化”
作者:
F. M. Mück;J. A. Baus;C. Burschka;R. Tacke
The donor‐stabilized silylene [iPrNC(NiPr2)NiPr]2Si (2) reacts with PhEl−ElPh (El=S, Se) to form the respective cationic five‐coordinate bis(guanidinato)silicon(IV) complexes {[iPrNC(NiPr2)NiPr]2SiSPh}+PhS−(4) and {[iPrNC (NiPr2)NiPr]2SiSePh}+PhSe−(5). Compounds4and5were characterized by crystal structure analyses and NMR spectroscopic studies in the solid state.
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DOI:
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发表时间:
2005
期刊:
影响因子:
--
作者:
Oliver Seiler;Matthias W. Büttner;Martin Penka;R. Tacke
通讯作者:
R. Tacke
影响因子:
--
作者:
Felix M. Mück;Dorit Kloß;Johannes A. Baus;C. Burschka;R. Tacke
通讯作者:
R. Tacke
影响因子:
--
作者:
Bastian Theis;S. Metz;C. Burschka;R. Bertermann;Stefan Maisch;R. Tacke
通讯作者:
R. Tacke
影响因子:
4.9
作者:
Phillip Steiniger;G. Bendt;D. Bläser;C. Wölper;S. Schulz
通讯作者:
S. Schulz
影响因子:
8.4
作者:
Sen, Sakya S.;Khan, Shabana;Roesky, Herbert W.
通讯作者:
Roesky, Herbert W.