Hydrothermal synthesis of rare-earth fluoride nanocrystals

Hydrothermal synthesis of rare-earth fluoride nanocrystals
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DOI:
10.1021/ic051683s
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发表时间:
2006-08-21
影响因子:
4.6
通讯作者:
Li, Yadong
Li, Yadong
中科院分区:
化学2区
文献类型:
--
作者:
Wang, Xun;Zhuang, Jing;Li, Yadong

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本文采用水热合成法制备了一类稀土氟化物纳米晶,其生长模式随离子半径的减小而逐渐改变,可作为研究稀土纳米晶可控生长机理的模型体系。此外,我们证明了这些纳米晶体的功能化通过掺杂,这显示了可见的肉眼绿色上转换发射,并可能在生物标记领域中找到应用。
In this paper, a hydrothermal synthetic route has been developed to prepare a class of rare-earth fluoride nanocrystals, which have shown gradual changes in growth modes with decreasing ionic radii and may serve as a model system for studying the underlying principle in the controlled growth of rare-earth nanocrystals. Furthermore, we demonstrate the functionalization of these nanocrystals by means of doping, which have shown visible-to-the-naked-eye green up-conversion emissions and may find application in biological labeling fields.