Formation of a core?shell droplet in a thermo-responsive ionic liquid/water mixture by using optical tweezers

Formation of a core?shell droplet in a thermo-responsive ionic liquid/water mixture by using optical tweezers
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使用光镊在热响应离子液体/水混合物中形成核壳液滴

DOI:
10.1039/d2cc02699f
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发表时间:
2022
影响因子:
4.9
通讯作者:
Yuyama Ken-ichi
Yuyama Ken-ichi
中科院分区:
化学2区
文献类型:
--
作者:
Tanaka Maho;Tsuboi Yasuyuki;Yuyama Ken-ichi

文献摘要

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许多化学和生物过程涉及相分离;然而,控制这是具有挑战性的。在这里,我们展示了局部相分离,使用光镊在热响应离子液体/水溶液。在近红外激光照射时,在焦点处形成单个液滴。液滴具有由高度浓缩的离子液体组成的核心。从光学势和热势的空间分布角度讨论了核壳液滴的形成机理。
Many chemical and biological processes involve phase separation; however, controlling this is challenging. Here, we demonstrate local phase separation using optical tweezers in a thermo-responsive ionic liquid/water solution. Upon near-infrared laser irradiation, a single droplet is formed at the focal spot. The droplet has a core consisting of highly concentrated ionic liquid. The mechanism of the core–shell droplet formation is discussed in view of the spatial distribution of optical and thermal potentials.