Selective crystallization of dysprosium complex from neodymium/dysprosium mixture enabled by cooperation of coordination and crystallization
Selective crystallization of dysprosium complex from neodymium/dysprosium mixture enabled by cooperation of coordination and crystallization
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DOI：
10.1039/d1cc06174g
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发表时间：
2021-12-31
影响因子：
4.9
通讯作者：
Iki, Nobuhiko
中科院分区：
文献类型：
--
作者：
Masuya-Suzuki, Atsuko;Hosobori, Koji;Iki, Nobuhiko
设计分子水平的Ln（3+）分离系统仍然是开发下一代分离方法的一个挑战。在这里，我们报告了基于结晶的Nd3+/Dy3+分离使用三足席夫碱配体。通过配位和结晶过程的配合，实现了Dy3+配合物的高选择性结晶。
Designing a molecular-level Ln(3+) separation system remains a challenge for developing next-generation separation methodologies. Herein, we report crystallization-based Nd3+/Dy3+ separation using a tripodal Schiff base ligand. Highly selective crystallization of the Dy3+ complex was enabled by cooperation between the coordination and crystallization processes.