Glass-phase coordination polymer displaying proton conductivity and guest-accessible porosity.
Glass-phase coordination polymer displaying proton conductivity and guest-accessible porosity.
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DOI：
10.1039/c9cc02744k
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发表时间：
2019-07
影响因子：
4.9
通讯作者：
M. Inukai;Y. Nishiyama;Kayako Honjo;Chinmoy Das;S. Kitagawa;S. Horike
中科院分区：
文献类型：
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作者：
M. Inukai;Y. Nishiyama;Kayako Honjo;Chinmoy Das;S. Kitagawa;S. Horike
我们描述了一种具有质子导电性和客体可通透性的配位聚合物的结晶和玻璃态的制备方法。EXAFS和固体核磁共振分析表明，焦磷酸盐和磷酸根离子是玻璃中主要的质子转运体，5-氯-1H-苯并咪唑均匀分布在玻璃中提供了孔隙率。
We describe the preparation of the crystalline and glassy state of a coordination polymer displaying proton conduction and guest-accessible porosity. EXAFS and solid-state NMR analyses indicated that pyrophosphate and phosphate ions are the main proton transporters in the glass and that homogeneously distributed 5-chloro-1H-benzimidazole in the glass provides the porosity.